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«Safety Data Sheet Material Name: Crushed Stone Synonyms: Construction Aggregate Section 1 – Product and Company Identification Manufacturer ...»

Safety Data Sheet

Material Name: Crushed Stone

Synonyms: Construction Aggregate

Section 1 – Product and Company Identification

Manufacturer Information

Peckham Industries Inc.

20 Haarlem Ave.

White Plains, NY 10603

Phone: 914-949-2000

www.peckham.com

Section 2 – Hazardous Identification

GHS Classification:

Acute Toxicity Oral – Category 4

Skin Corrosion/Irritation – Category 2

Eye Damage/Irritation – Category 2

Carcinogenicity – Category 1 Specific Target Organ Toxicity Repeat Exposure – Category 1

GHS LABEL ELEMENTS

Symbol(s) Signal Word Danger Hazard Statements Harmful if swallowed.

Causes skin and eye irritation.

May cause cancer.

Causes damage to organs (lungs) through prolonged or repeated exposure.

Precautionary Statements Prevention Wash thoroughly after handling.

Do not eat, drink or smoke when using this product.

Obtain special instructions before use.

Do not handle until all safety precautions have been read and understood.

Wear protective gloves/protective clothing/eye protection/face protection.

Do not breath dust.

_______________________________________________________________

Page 1 of 7 Issue Date: 02/19/15 Revision 1.0000 Print Date: 02/19/15 Safety Data Sheet Material name: Crushed Stone Response If swallowed: Call a poison center/doctor if you feel unwell. Rinse mouth.

If on skin: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse.

If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.

Continue rinsing. If eye irritation persists: Get medical advice/attention.

Storage Store in an appropriate container or containment structure.

Disposal Dispose of contents/container in accordance with local/regional/nation/international regulations.

Section 3 – Composition/ Information on Ingredients CAS # Component Percent Not Available Metamorphic, Igneous, or Sedimentary Rock 97-99 14808-60-7 Quartz 1 Component Information/ Information on Non-Hazardous Components General Product Information Trace Elements: These materials are mined from the earth. Trace amounts of naturally occurring elements might be detected during chemical analysis of these materials.

Section 4 – First Aid Measures First Aid: Eyes Immediately flush eyes thoroughly with water. Call physician if irritation persists.

First Aid: Skin Wash skin with soap and water. Call physician if irritation persists.

First Aid: Ingestion Do not induce vomiting. If conscious, have the victim drink plenty of water and call a physician for medical advice.

First Aid: Inhalation Remove to fresh air. Seek medical help if coughing and other symptoms do not subside.

Section 5 – Fire Fighting Measures General Fire Hazards See Section 9 for Flammability Properties.

None Hazardous Combustion Products None Extinguishing Media Use appropriate extinguishing media for surrounding fire.

Unsuitable Extinguishing Media None

–  –  –

Fire Fighting Equipment/Instructions Firefighters should wear full protective gear.

Section 6 – Accidental Release Measures Recovery and Neutralization Avoid actions that cause dust to become airborne. Avoid inhalation of dust and contact with skin. Wear appropriate personal protective equipment as described in Section 8.

Materials and Methods for Clean-Up Vacuum cleaning is the preferred method for the dry fine materials. Avoid dry sweeping which creates dust.

Apply water spray to prevent airborne dust. Scrape up wet material and place in an appropriate container.

Emergency Measures Isolate area. Keep unnecessary personnel away.

Personal Precautions and Protective Equipment Wear protective equipment and clothing during clean-up.

Environmental Precautions None Prevention of Secondary Hazards None Section 7 – Handling and Storage Handling Procedures Wash thoroughly after exposure to dust. Promptly remove dusty clothing and launder before use.

Storage Procedures Normal temperatures and pressures do not affect the material.

Incompatibilities None Section 8 – Exposure Controls/ Personal Protection Component Exposure Limits Quartz (14808-60-7) ACGIH: 0.025 mg/m3 TWA (respirable fraction) NIOSH: 0.05 mg/m3 TWA (respirable dust) Engineering Measures Use local exhaust or general dilution ventilation to control exposure within applicable limits.

Personal Protective Equipment: Respiratory Avoid actions that cause dust exposure to occur. Use local or general ventilation to control exposures below applicable exposure limits. NIOSH or MSHA approved particulate filter respirators should be used in the context of respiratory protection program meeting the requirements of the OSHA respiratory protection standard [29 CFR 1910.134] to control exposures when ventilation or other controls are inadequate or discomfort or irritation is experienced. Respirator and/or filter cartridge selection should be based on American National Standards Institute (ANSI) Standards Z88.2 Practices for Respiratory Protection.

Personal Protective Equipment: Hands Where prolonged exposure to products might occur, wear impervious gloves to eliminate skin contact.





–  –  –

Personal Protective Equipment: Eyes When engaged in activities where ingredients could contact the eye, wear safety glasses with side shields or goggles. In extremely dusty environments and unpredictable environments, wear unvented or indirectly vented goggles to avoid eye irritation or injury. Contact lenses should not be worn when working with ingredients.

Personal Protective Equipment: Skin and Body Normal work clothing (long sleeved shirts and long pants) is recommended.

Section 9 – Physical & Chemical Properties

–  –  –

Section 10 – Chemical Stability & Reactivity Information Chemical Stability This is a stable material.

Hazardous Reaction Potential Will not occur.

Conditions to Avoid Contact with powerful oxidizing agents such as fluorine, boron trifluoride, chlorine trifluoride, and oxygen difluoride may cause fire and/or explosions. Silica dissolves in hydrofluoric acid producing gas- silicon ictrafluoride.

Incompatible Products None.

Hazardous Decomposition Products None.

Section 11 – Toxicological Information Acute Toxicity Component Analysis – LD50/LC50 Quartz (14808-60-7) Oral LD50 Rat 500 mg/kg Potential Health Effects: Skin Corrosion Property/Stimulativeness This product can cause abrasion and irritation to the skin.

–  –  –

Potential Health Effects: Eye Critical Damage/Stimulativeness Exposure to airborne dust during the handling of this product may cause immediate or delayed irritation.

Potential Health Effects: Ingestion This product can cause gastrointestinal irritation if ingested.

Potential Health Effects: Inhalation The ingredients in this product could contain crystalline silica. Exposure to these ingredients in excess of the applicable TLV or PEL may cause or aggravate other lung conditions. Exposure may cause irritation to the moist mucous membranes of the nose, throat, and upper respiratory system.

Respiratory Organs Sensitization/Skin Sensitization This product is not reported to have any sensitization effects.

Generative Cell Mutagenicity This product is not reported to have any mutagenic effects.

Carcinogenicity A. General Product Information May cause cancer.

Exposures to respirable crystalline silica are not expected during the normal use of this product. Prolonged and repeated exposure to airborne free respirable crystalline silica can result in lung disease and/or lung cancer. IARC states that crystalline silica in the form of quartz or cristobalite from occupational sources is carcinogenitic to humans (Group 1).

B. Component Carcinogenicity Quartz (14808-60-7) ACGIH: A2- Suspected Human Carcinogen NIOSH: Potential occupational carcinogen NTP: Known Human Carcinogen (respirable size) (Select Carcinogen) IARC: Monograph 100C [2012](listed under Crystalline silica inhaled in the form of quartz or cristobalite from occupational sources); Monograph 68 [1997] (Group 1(carcinogenic to humans)).

Reproductive Toxicity This product is not reported to have any reproductive toxicity effects.

Specified Target Organ General Toxicity: Single Exposure This product is not reported to have any single exposure specific target organ toxicity effects.

Specified Target Organ General Toxicity: Repeated Exposure Causes damage to organs (lungs) through prolonged or repeated exposure.

Aspiration Respiratory Organs Hazard This product is not reported to have any aspiration hazard effects.

Section 12 – Ecological Information Ecotoxicity A. General Product Information This product is not reported to have any ecotoxicity effects. Dust can cause soiling and damage sensitive vegetation after prolonged exposure. Aggregates are classified inert and not considered to pose ecological concern.

–  –  –

B. Component Analysis – Ecotoxicity – Aquatic Toxicity No ecotoxicity data are available for this product's components.

Persistence/Degradability No information available for the product.

Bioaccumulation No information available for the product.

Mobility in Soil No information available for this product.

Section 13 – Disposal Considerations Waste Disposal Instructions See Section 7 for Handling Procedures. See Section 8 for Personal Protective Equipment recommendations.

Disposal of Contaminated Containers or Packing Dispose of contents/container in accordance with local/regional/national/international regulations.

Section 14 – Transportation Information DOT Information Shipping Name: Not Regulated Additional Info: Dry fine materials best transported by bulk tanker or sealed bags. Aggregates should be sheeted or conditioned with water to minimize dust.

Section 15 – Regulatory Information Regulatory Information US Federal Regulations Component Analysis None of this product's components are listed under SARA Section 302 (40 CFR 335 Appendix A), SARA Section 313 (40 CFR 372.65), or CERCLA (40 CFR 302.4).

State Regulations Component Analysis – State

The following components appear on one or more of the following state hazardous substances lists:

–  –  –

NFPA/HMIS Definitions: 0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme Protective Equipment: Safety glasses, gloves Key/Legend EPA = Environmental Protection Agency; TSCA = Toxic Substance Control Act; ACGIH = American Conference of Governmental Industrial Hygienists; IARC = International Agency for Research on Cancer; NIOSH = National Institute for Occupational Safety and Health; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration., NJTSR = New Jersey Trade Secret Registry.

Literature References None Other Information

SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE

MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE OR CONCERNING THE ACCURACY

OF ANY INFOMATION PROVIDED BY PECKHAM, except that the product shall conform to contracted specifications. The information provided herein was believed by Peckham Industries to be accurate at the time of preparation or prepared from sources believed to be reliable, but it is the responsibility of the user to investigate and understand other pertinent sources of information to comply with all laws and procedures applicable to the safe handling and use of the product and to determine the suitability of the product for its intended use. Buyer's exclusive remedy shall be for damages and no claim of any kind, whether as to product delivered or for nondelivery of product, and whether based on contract, breach of warranty, negligence, or otherwise shall be greater in amount than the purchase price of the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, negligence or otherwise.

–  –  –





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